Thermal behaviour of transition metal complexes of dithiocarbazic esters. II |
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Authors: | L Suber F Tarli G Chiozzini M Zugarini C Riccucci |
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Institution: | (1) Istituto di Teoria e Struttura Elettronica e Comportamento Spettrochimico dei Composti di Coordinazione del C.N.R., 00016 Monterotondo Stazione, Italy |
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Abstract: | A thermal study (simultaneous TG and DTA measurements) was carried out on the dithiocarbazic ester complexes MN3CH2R1N2C1(S)SCH3]2, where M=Ni, Pt; R1=C6H5. The following disproportionation reaction occurs in the solid state: II is formed through deprotonation of the CH2 group bound to N3, whereas III is formed through protonation of N3.The influence of inductive and/or steric effects on the mechanism of this reaction is discussed, taking into account the electrochemical and X-ray data on the complexes PtNRNC(S)SR']2 with differentR substituents: R=H, Ph, CH2Ph, CH2C5H11, CH(CH3)2, C(CH3)3; R =CH3, CH2Ph.These results accord with the behaviour of the same complexes in solution.
Zusammenfassung Dithiokarbamidsäureesterkomplexe MN3CH2R1N2C1(S)SCH3]2 mit M=Ni, Pt und R1=C6H5 wurden thermisch untersucht. Im festen Zustand spielt sich folgende Disproportionierungsreaktion ab: II wird durch Deprotonierung der an N3 gebundenen CH2 Gruppe und III durch Protonierung des Atoms N2 gebildet. Unter Zuhilfenahme der elektrochemischen und Röntgendaten der Komplexe PtNRNC(S)SR']2 mit verschiedenen Substituenten R: R=H, Ph, CH2Ph, CH2C5H11, CH(CH3)2, C(CH3)3 und R =CH3 bzw. CH2Ph wurde der Einfluß von induktiven und/or sterischen Effekten auf den Reaktionsmechanismus diskutiert. Diese Ergebnisse stehen in Übereinstimmung mit dem Verhalten der Komplexe in Lösung.
![Rcy](/content/p20t50045q2n2g85/xxlarge1056.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![yucy](/content/p20t50045q2n2g85/xxlarge1102.gif) ![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![Scy](/content/p20t50045q2n2g85/xxlarge1057.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![vcy](/content/p20t50045q2n2g85/xxlarge1074.gif) ![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![shchcy](/content/p20t50045q2n2g85/xxlarge1097.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ycy](/content/p20t50045q2n2g85/xxlarge1099.gif) ![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) 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1=C6H5. ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![vcy](/content/p20t50045q2n2g85/xxlarge1074.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![yacy](/content/p20t50045q2n2g85/xxlarge1103.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![khcy](/content/p20t50045q2n2g85/xxlarge1093.gif) 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![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![vcy](/content/p20t50045q2n2g85/xxlarge1074.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) : ![Pcy](/content/p20t50045q2n2g85/xxlarge1055.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) II ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![bcy](/content/p20t50045q2n2g85/xxlarge1073.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![vcy](/content/p20t50045q2n2g85/xxlarge1074.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) CH2 ![gcy](/content/p20t50045q2n2g85/xxlarge1075.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) , ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![vcy](/content/p20t50045q2n2g85/xxlarge1074.gif) ![yacy](/content/p20t50045q2n2g85/xxlarge1103.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) N3, ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) III![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![vcy](/content/p20t50045q2n2g85/xxlarge1074.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) N2. ![Vcy](/content/p20t50045q2n2g85/xxlarge1042.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![yacy](/content/p20t50045q2n2g85/xxlarge1103.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![tscy](/content/p20t50045q2n2g85/xxlarge1094.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ycy](/content/p20t50045q2n2g85/xxlarge1099.gif) (![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![chcy](/content/p20t50045q2n2g85/xxlarge1095.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![fcy](/content/p20t50045q2n2g85/xxlarge1092.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![khcy](/content/p20t50045q2n2g85/xxlarge1093.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![ecy](/content/p20t50045q2n2g85/xxlarge1101.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![tscy](/content/p20t50045q2n2g85/xxlarge1094.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![bcy](/content/p20t50045q2n2g85/xxlarge1073.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![zhcy](/content/p20t50045q2n2g85/xxlarge1078.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) , ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![khcy](/content/p20t50045q2n2g85/xxlarge1093.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![ecy](/content/p20t50045q2n2g85/xxlarge1101.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![khcy](/content/p20t50045q2n2g85/xxlarge1093.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![chcy](/content/p20t50045q2n2g85/xxlarge1095.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![gcy](/content/p20t50045q2n2g85/xxlarge1075.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![gcy](/content/p20t50045q2n2g85/xxlarge1075.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![fcy](/content/p20t50045q2n2g85/xxlarge1092.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![chcy](/content/p20t50045q2n2g85/xxlarge1095.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ycy](/content/p20t50045q2n2g85/xxlarge1099.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) PtNRNC(S)SR ]2, ![gcy](/content/p20t50045q2n2g85/xxlarge1075.gif) R=![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![chcy](/content/p20t50045q2n2g85/xxlarge1095.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ycy](/content/p20t50045q2n2g85/xxlarge1099.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![fcy](/content/p20t50045q2n2g85/xxlarge1092.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![chcy](/content/p20t50045q2n2g85/xxlarge1095.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![chcy](/content/p20t50045q2n2g85/xxlarge1095.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) , aR =![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![bcy](/content/p20t50045q2n2g85/xxlarge1073.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) . ![Pcy](/content/p20t50045q2n2g85/xxlarge1055.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![chcy](/content/p20t50045q2n2g85/xxlarge1095.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![ycy](/content/p20t50045q2n2g85/xxlarge1099.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![zcy](/content/p20t50045q2n2g85/xxlarge1079.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![softcy](/content/p20t50045q2n2g85/xxlarge1100.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![gcy](/content/p20t50045q2n2g85/xxlarge1075.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![ucy](/content/p20t50045q2n2g85/xxlarge1091.gif) ![yucy](/content/p20t50045q2n2g85/xxlarge1102.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![vcy](/content/p20t50045q2n2g85/xxlarge1074.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![dcy](/content/p20t50045q2n2g85/xxlarge1076.gif) ![ncy](/content/p20t50045q2n2g85/xxlarge1085.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![ecy](/content/p20t50045q2n2g85/xxlarge1101.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![icy](/content/p20t50045q2n2g85/xxlarge1080.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![mcy](/content/p20t50045q2n2g85/xxlarge1084.gif) ![pcy](/content/p20t50045q2n2g85/xxlarge1087.gif) ![lcy](/content/p20t50045q2n2g85/xxlarge1083.gif) ![iecy](/content/p20t50045q2n2g85/xxlarge1077.gif) ![kcy](/content/p20t50045q2n2g85/xxlarge1082.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) ![rcy](/content/p20t50045q2n2g85/xxlarge1088.gif) ![acy](/content/p20t50045q2n2g85/xxlarge1072.gif) ![scy](/content/p20t50045q2n2g85/xxlarge1089.gif) ![tcy](/content/p20t50045q2n2g85/xxlarge1090.gif) ![vcy](/content/p20t50045q2n2g85/xxlarge1074.gif) ![ocy](/content/p20t50045q2n2g85/xxlarge1086.gif) .
We thank prof. A. La Ginestra for many helpful discussions on the various aspects of this work. |
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