| 以苯荒酸为配体的[Bu4N]2[W2Ag3S8(C6H5CSS)]钨银硫簇合物的合成和晶体结构 |
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| 引用本文： | 金祥林,倪海洪,汤卡罗,唐有祺.以苯荒酸为配体的[Bu4N]2[W2Ag3S8(C6H5CSS)]钨银硫簇合物的合成和晶体结构[J].高等学校化学学报,1992,13(6):724. |
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| 作者姓名： | 金祥林 倪海洪 汤卡罗 唐有祺 |
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| 作者单位： | 北京大学物理化学研究所, 北京, 100871 |
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| 摘 要： | 标题化合物由(C6H5CSS)-(Bu4N)+、AgNO3和(NH4)2WS4、Bu4NBr反应制备,用X射线单晶衍射法测定其晶体结构。
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| 关 键 词： | 钨银硫簇合物 苯荒酸 合成 晶体结构 |
| 收稿时间： | 1992-01-11 |
Synthesis and Crystal Structure of [Bu_4N]_2[W_2Ag_3S_8(C_6H_5CSS)] with Dithiobenzoic Acid as the Ligand |
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| JIN Xiang-lin,NI Hai-hong,TANG Ka-luo,TANG You-qi.Synthesis and Crystal Structure of [Bu_4N]_2[W_2Ag_3S_8(C_6H_5CSS)] with Dithiobenzoic Acid as the Ligand[J].Chemical Research In Chinese Universities,1992,13(6):724. |
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| Authors: | JIN Xiang-lin NI Hai-hong TANG Ka-luo TANG You-qi |
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| Institution: | Institute of Physical Chemistry, Peking University, Beijing, 100871 |
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| Abstract: | The title compound was prepared from the reaction of (NH4)2WS4, AgNO3, (Bu4N)+(C6H5CSS)- and Bu4NBr in CH3CN solution, then crystalized in CH3CN/MeOH.It crystalizes in monoclinic space group P21/c with the following crystal parameters, a =1.8945 (12) nm, b=1.1963(10) nm, c=2.5660(14)nm, β=98.13(5)°, V=5.757(6) nm3, Dc=1.830 g/cm3, Z=4.The final R=0.0827 for 3329 reflections.The W2Ag3 unit in the anion W2Ag3S8(C6H5CSS) forms a five-membered ring. |
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| Keywords: | W-Ag-S cluster complex Dithiobenzoic acid Synthesis Crystal structure |
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