Base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over Pt/C catalysts synthesized by pulse alternating current technique |
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Authors: | Daria V. Chernysheva Victor A. Klushin Alexander F. Zubenko Lyudmila S. Pudova Oleg A. Kravchenko Victor M. Chernyshev Nina V. Smirnova |
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Affiliation: | Department of Technology, M. I. Platov South-Russian State Polytechnic University, 346428 Novocherkassk, Russian Federation |
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Abstract: | The Pt/C catalysts with various Pt content (5-30 wt%) synthesized via electrochemical pulse alternating current technique have been evaluated for the base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid. The higher Pt content in the catalyst (30 wt%) provides the product yield up to 65% upon performing the process in concentrated (~0.1 M) aqueous solutions of the substrate. |
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Keywords: | Corresponding author. |
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