A comparative study of AgX (X = Cl(-), Br(-), I(-) and N(3)(-)) solid-phase reactors for flow-injection determination of cyanide in electroplating wastewater. |
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Authors: | Meissam Noroozifar Mozhgan Khorasani-Motlagh Aboozar Taheri Rohollah Zare-Dorabei |
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Institution: | Analytical Research Laboratory, Department of Chemistry, University of Sistan & Baluchestan, Zahedan, Iran. mnoroozifar@chem.usb.ac.ir |
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Abstract: | In this study, a rapid flow injection-flame atomic absorption spectrometry for cyanide detection was developed. Different AgX (where X is Cl(-), Br(-), I(-) and N(3)(-)) solid-phase reagents (SPR) were tested for indirect determination of cyanide. In a single-line FIA system, the cyanide was allowed to react with AgX SPR, which in turn changed Ag ions in AgX to silver cyanide complexes in a sodium hydroxide carrier stream. The eluent containing the analyte as silver cyanide complexes was measured by FAAS. The calibration curve was linear up to 30 mg l(-1) with a detection limit of 0.05 mg l(-1) for cyanides. The sampling rate and the relative standard deviation were <1.09% and >200 h(-1), respectively. The method was applied to the determination of cyanide in electroplating wastewater. |
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