Part I. epoxydes diterpeniques : synthese et reactivite d'epoxydes derives d'acides resiniques |
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| Authors: | B Papillaud F Tiffon M Taran BArreguy-San Miguel B Delmond |
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| Institution: | Institut Du Pin - Université de Bordeaux I 351, cours de la Libération - 33405 Talence CedexFrance |
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| Abstract: | Epoxidation of methyl esters of resin acids with the pimarane skeleton with p-nitroperbenzoic acid has permitted the isolation of epoxides of the intracyclic double bond. Allylic diterpenic alcohols were obtained by acid-catalysed isomerisation of diterpene epoxides, and the action of Collins reagent on these allylic alcohols has been studied. |
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