Mass Spectra of New Heterocycles. XVII. Main Fragmentation Routes of Molecular Ions of 4-Alkoxy-5-amino-3-methylthiophene-2-carbonitriles under Electron and Chemical Ionization |
| |
Authors: | L V Klyba N A Nedolya E R Sanzheeva O A Tarasova |
| |
Institution: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia |
| |
Abstract: | For the first time decomposition was investigated of 4-alkoxy-5-amino-3-methylthiophene-2-carbonitriles under the conditions of electronic (70 eV) and chemical (reagent gas methane) ionization. At the electronic ionization the compounds under study except for 4-(1-ethoxyethoxy) and 4-(ferrocenylmethoxy) derivatives] form stable molecular ions that decompose mainly by the cleavage of an alkyl radical from the alkoxy-substituent. Further fragmentation of the arising ion M–Alk]+ depends on the substituent nature in the amino group. In the mass spectrum of 4-(ferrocenylmethoxy)-substituted thiophene peaks of the ion FcCH2]+ and its fragmentation products prevail. In the mass spectra of chemical ionization predominant peaks belong to ions M+·, M + H]+ and M + C2H5]+, and fragment ions are absent. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |