Quadrupolar interaction in iridium cyanide mixed-ligands complexes in alkali halide matrices by ESR spectroscopy |
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| Authors: | N. M. Pinhal N. V. Vugman |
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| Affiliation: | 1. Instituto de Fisica, Universidade Federal do Rio de Janeiro, Ilha do Fund?o, Cidade Universitária, Bloco A, C.T., 21945, Rio de Janeiro, Brazil
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| Abstract: | ![]()
Quadrupolar interactions in [IR(CN)5]3−, [Ir(CN)5Cl]4− and [Ir(CN)4Cl2]4− paramagnece a complexes in alkali halide host lattices are systematically analysed by ESR spectroscopy. The measured quadrupolar interactions are shown to have no clear correlation to the measured unpaired electron populations. |
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