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| Synthesis,Spectroscopic Properties and Crystal Structure of 3,3＇-（Anthracene-9,10-diyl）bis（1-phenylpropan-1-one） | |
| 引用本文： | NING Guo-Hong,LI Yi-Zhi,YU Shu-Yan. Synthesis,Spectroscopic Properties and Crystal Structure of 3,3＇-（Anthracene-9,10-diyl）bis（1-phenylpropan-1-one）[J]. 结构化学, 2010, 29(12): 1780-1783 |
| 作者姓名： | NING Guo-Hong LI Yi-Zhi YU Shu-Yan |
| 作者单位： | [1]Laboratory for Self-assembly Chemistry, Department of Chemistry, Renmin University of China, Beijing 100872, China [2]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China [3]Department of Chemistry, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093, China |
| 基金项目： | Supported by the National Natural Science Foundation of China （No. 20772152） and the State Key Laboratory of Structural Chemistry |
| 摘 要： | The compound 3,3'-(anthracene-9,10-diyl)bis(1-phenylpropan-1-one)(C32H26O2,Mr=442.55) has been synthesized by the reaction of 2,2'-(anthracene-9,10-diylbis(methy-lene))bis(1,3-diphenylpropane-1,3-dione) with CsCO3,and its structure was characterized by 1H NMR and single-crystal X-ray diffraction.The crystal of the title compound belongs to monoclinic,space group P21/c with a=9.154(3),b=5.2777(16),c=24.897(7) nm,β=107.337(10)°,Z=2 and V=1.1482 nm3.X-ray analysis indicates that an intermolecular hydrogen bond C(8)-H(8A)…O(1),weak C-H···π between H(9A) and the centre of anthracene rings and weak π-π interactions between two anthracene ring planes are observed. |
| 关 键 词： | 晶体结构 光谱性质 合成 单晶X射线衍射 蒽 X射线分析 相互作用 化合物 |
Synthesis,Spectroscopic Properties and Crystal Structure of 3,3'-(Anthracene-9,10-diyl)bis(1-phenylpropan-1-one) |
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| NING Guo-Hong,LI Yi-Zhi,YU Shu-Yan. Synthesis,Spectroscopic Properties and Crystal Structure of 3,3'-(Anthracene-9,10-diyl)bis(1-phenylpropan-1-one)[J]. Chinese Journal of Structural Chemistry, 2010, 29(12): 1780-1783 | |
| Authors: | NING Guo-Hong LI Yi-Zhi YU Shu-Yan |
| Affiliation: | NING Guo-Honga LI Yi-Zhic YU Shu-Yana,b a(Laboratory for Self-assembly Chemistry,Department of Chemistry,Renmin University of China,Beijing 100872,China) b(State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China) c(Department of Chemistry,State Key Laboratory of Coordination Chemistry,Coordination Chemistry Institute,Nanjing University,Nanjing 210093,China) |
| Abstract: | The compound 3,3'-(anthracene-9,10-diyl)bis(1-phenylpropan-1-one) (C32H26O2,Mr=442.55) has been synthesized by the reaction of 2,2'-(anthracene-9,10-diylbis(methy-lene))bis(1,3-diphenylpropane-l,3-dione) with CsCO3,and its structure was characterized by 1H NMR and single-crystal X-ray diffraction.The crystal of the title compound belongs to monoclinic,space group P21/C with a=9.154(3),b=5.2777(16),c=24.897(7) nm,β= 107.337(10)°,Z=2 and V= 1.1482 nm3.X-ray analysis indicates that an intermolecular hydrogen bond C(8)-H(8A)…O(1),weak C-H…π between H(9A) and the centre of anthracene rings and weak π-π interactions between two anthracene ring planes are observed. |
| Keywords: | X-ray diffraction crystal structure synthesis C-H…π interaction |
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