The effect of pressure on the oxidation of benzhydrol by alkaline permanganate期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

The effect of pressure on the oxidation of benzhydrol by alkaline permanganate

Authors:	Neil S. Isaacs Karel A.H. Heremans

Affiliation:	Department of Chemistry, University of Reading, Reading, RG6 2AD Belgium;Department of Physical Chemistry, Catholic University of Leuven, 200D Leuven B3030, Belgium

Abstract:	The rate of oxidation of benzhydrol and benzhydrol-d to benzophenone by alkaline permanganate has been measured over a pH range 10 to 12.5 and pressures from 1 to 1000 bar. The pressure effect on the rate is small, Δ $V$ ^≠ = ?6 to ?8 cm³mol^?1. This is held to support a hydrogen atom transfer in the rate-determining step.

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