The isomerization of optically-active propargyl alcohols to terminal acetylenes. |
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| Authors: | MMark Midland Ronald L Halterman Charles A Brown Angela Yamaichi |
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| Institution: | Department of Chemistry, University of California, Riverside, CA 92521, USA;Department of Molecular and Chemical Dynamics, IBM Research Laboratory K34, San Jose, CA 95193, USA |
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| Abstract: | The isomerization of optically-active secondary propargyl alcohols, RCHOHCC(CH2)nCH3, to terminal acetylenic alcohols, RCHOH(CH2)n+1 C=CH, by potassium 3-aminopropylamide (KAPA) proceeds without loss of configuration at the hydroxy center. |
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