Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity |
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| Authors: | García Felipe Less Robert J McPartlin Mary Michalski Annette Mulvey Robert E Naseri Vesal Stead Matthew L Morán de Vega Ana Wright Dominic S |
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| Affiliation: | Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK. |
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| Abstract: | ![]()
The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li(4)·3thf}(4)(μ(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li(4) sites has negligible effect on the structural parameters. |
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