Redox troponization of 4-methyl-4-dibromomethyl-2,5-cyclohexadien-1-one by the action of Pd(PPh3)4 |
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Authors: | V. A. Nikanorov G. V. Gavrilova V. I. Rozenberg O. A. Reutov |
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Affiliation: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The feasibility of using gem-dihalomethyl-substituted cyclohexadienones in redox troponization reactions was shown in the case of the reaction of 4-methyl-4-dibromomethyl-2,5-cyclohexadien-1-one with Pd(PPh3)4, leading to the formation of 4-methy1-2,4,6-cycloheptatrien-1-one.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2345–2346, October, 1987. |
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