Local mobility of micelles of new cationic surfactants and their interactions with hydrophobically modified polyacrylamides

The local dynamics and organization of micelles of new long-chain cationic surfactants with saturated hydrocarbon fragments (from C₁₆ to C₂₂) are investigated via the EPR spin-probe technique. The local mobility of spin probes in the hydrocarbon core of a micelle changes insignificantly, while the order parameter noticeably increases with lengthening of the hydrocarbon fragment of the surfactant molecule. The specific features of the interaction of the surfactants with network junctions of the gels formed by two types of hydrophobically modified polyacrylamides??either containing charged groups (sodium acrylate) in the backbone or lacking these groups??are studied. In both cases, the local mobility of network junctions of the gel increases after the introduction of the surfactant (C₁₈). Moreover, for surfactant with a long alkyl group (C₂), the microscopic viscosity of the gel based on the uncharged polymer decreases, although the local mobility of the network junctions increases. Possible causes of the observed specific features are discussed.