The reaction of Ru3(CO)12 with HC9PPh2)3. Characterisation of Ru3(CO)9[HC(PPh2)3], and crystal and molecular structure of Ru3(CO)9[HC(PPh2)(PhPC6H4PPh)]·CHCl3 |
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| Authors: | Marjorie M Harding Barry S Nicholls Anthony K Smith |
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| Institution: | Department of Inorganic, Physical, and Industrial Chemistry, Donnan Laboratories, University of Liverpool, Liverpool L69 3BX Great Britain |
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| Abstract: | Reaction of Ru3(CO)12 with HC(PPh2)3 leads to a variety of products, two of which have been characterised. One is the symmetrically capped product Ru3(CO)9HC(PPh2)3], which was characterised spectroscopically. The second product was characterised crystallographically as Ru3(CO)9HC(PPh2)-(PhPC6H4PPh)]-CHCl3. |
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