A simple synthesis and purification of 1-ferrocenylalkyl alcohols |
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| Authors: | Bogusлaw Misterkiewicz |
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| Institution: | Institute of Organic Materials Science, Technical University of Radom, 26-600 Radom Poland |
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| Abstract: | An alternative method for the preparation of 1-ferrocenylalkyl alcohols has been developed. This involves condensation of ferrocene with carbonyl compounds in concentrated sulfuric acid and addition of the resulting solutions of 1-ferrocenylalkylium ions into aqueous sodium bicarbonate. The mixtures are then treated with thioglycolic acid and the S-(1-ferrocenylalkyl)thioglycolic acids purified via sodium salts and hydrolysed in the presence of copper powder to give 1-ferrocenylalkyl alcohols in good yields. |
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| Keywords: | To whom correspondence should be addressed |
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