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Alkoxy-derived fine powders of simple and complex oxides
Authors:M I Yanovskaya  N M Kotova  E P Kovsman  L A Golubko  A A Glushkova
Institution:(1) L. Ya. Karpov Institute of Physical Chemistry, Obukha st., 10, 103064 Moscow, Russia;(2) Research and Design Institute of Monomers, Prosp. Lenina, 106-a, 300600 Tula, Russia
Abstract:Fine powders of ZrO2, ZrO2-Y2O3, BaTi1–x Zr x O3 have been obtained by hydrolysis of alkoxides. For preparation of ZrO2-based materials precipitation from the partially hydrolyzed alkoxides solutions (sols) has been used. Barium titanate-based materials were obtained by hydroxide-alkoxide route with quick hydrolysis of titanium butoxide by excess of water on the first stage. The effect of the hydrolysis conditions on the size, shape, and specific surface area of the oxide powders has been discussed. Some considerations on comparison of the two hydrolytic techniques have been suggested.
Keywords:alkoxy-derived powders  hydrolysis of alkoxides  barium titanate  zirconium dioxide
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