Synthesis and Structural Characterization of [(C_2H_5)_4N][V~((V))O_2(OC_6H_3(OCH_3)CHNNCSNH_2)]·H_2O |
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作者姓名: | ZHOU Yin-Zhuang ZHANG Min ZI Feng-Lan LU Xiao-Ming LIU Shun-Cheng |
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作者单位: | ZHOU Yin-Zhuang ZHANG Min ZI Feng-Lan LU Xiao-Ming LIU Shun-Cheng (Department of Chemistry,Capital Normal University,Beijing 100037,China) JIN Xiang-Lin (Institute of Physical Chemistry,Beijing University,Beijing 100871,China) |
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摘 要: | 1 INTRODUCTIONAlthough vanadium plays an increasingly recognized role as a biometal1~4], little is known about the structure and function of vanadium compounds in living organisms. A classical and nevertheless rapidly developing field of application for oxovanadates and related compounds is their use as catalysts in polymerization and oxidation reactions5,6], and recent interest has focused on oxovanadates as model compounds for the interaction of oxovanadates with the active sites of en…
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