2,5,8,11-Tetraboronic ester perylenediimides: a next generation building block for dye-stuff synthesis |
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| Authors: | Battagliarin Glauco Li Chen Enkelmann Volker Müllen Klaus |
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| Institution: | Max Planck Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz, Germany. |
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| Abstract: | Via an unprecedentedly reported ruthenium catalyzed reaction, an efficient and straightforward method was developed for the synthesis of 2,5,8,11-tetraboronate perylenediimide derivatives. A possible reaction mechanism is proposed. The synthesis of 2,5,8,11-tetra-iodo and tetra-amino perylenediimides derivatives is also reported. |
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