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Small-angle neutron-scattering studies on nonaqueous dispersions Part 5: Magnesium carbonate dispersions in hydrocarbon media
Authors:R. H. Ottewill  E. Sinagra  I. P. MacDonald  J. F. Marsh  R. K. Heenan
Affiliation:(1) School of Chemistry, University of Bristol, Cantock's Close, BS8 1TS Bristol, UK;(2) Exxon Chemical Limited, Abingdon, Oxfordshire, UK;(3) ISIS, Rutherford-Appleton Laboratories, Chilton, Oxfordshire, UK
Abstract:
A method is described for the preparation of magnesium carbonate particles in a nonaqueous hydrocarbon environment. The particles were stabilised in the colloidal sense by the adsorption of an alkyl-aryl sulphonic acid. The particle morphology and particle-size distribution were examined by small-angle neutron scattering. It was concluded that the particle structure was of the coreshell type, with a core particle of basic magnesium carbonate, radius ca. 40 Å, and a shell of thickness ca. 13 Å. The results suggested that the latter was predominantly that of the alkyl-aryl part of the stabilising moiety.
Keywords:Magnesium carbonate dispersions  core-shell morphology  smallangle neutron scattering  nonaqueous dispersions
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