Small-angle neutron-scattering studies on nonaqueous dispersions Part 5: Magnesium carbonate dispersions in hydrocarbon media |
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Authors: | R. H. Ottewill E. Sinagra I. P. MacDonald J. F. Marsh R. K. Heenan |
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Affiliation: | (1) School of Chemistry, University of Bristol, Cantock's Close, BS8 1TS Bristol, UK;(2) Exxon Chemical Limited, Abingdon, Oxfordshire, UK;(3) ISIS, Rutherford-Appleton Laboratories, Chilton, Oxfordshire, UK |
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Abstract: | ![]() A method is described for the preparation of magnesium carbonate particles in a nonaqueous hydrocarbon environment. The particles were stabilised in the colloidal sense by the adsorption of an alkyl-aryl sulphonic acid. The particle morphology and particle-size distribution were examined by small-angle neutron scattering. It was concluded that the particle structure was of the coreshell type, with a core particle of basic magnesium carbonate, radius ca. 40 Å, and a shell of thickness ca. 13 Å. The results suggested that the latter was predominantly that of the alkyl-aryl part of the stabilising moiety. |
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Keywords: | Magnesium carbonate dispersions core-shell morphology smallangle neutron scattering nonaqueous dispersions |
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