Nickel-catalyzed decarbonylative addition of phthalimides to alkynes |
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| Authors: | Kajita Yuichi Matsubara Seijiro Kurahashi Takuya |
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| Affiliation: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan. |
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| Abstract: | ![]()
An intermolecular nickel-catalyzed addition reaction has been developed where N-arylphthalimides react with alkynes to afford substituted isoquinolones. A mechanistic rationale is proposed, implying nucleophilic attack of Ni(0) to an amide as the primary step of the catalytic cycle. |
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