Extended universal correlation diagrams for the quantum mechanical one-electron two-centre problem |
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Authors: | K. Helfrich |
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Affiliation: | 1. Theoretische Chemie, I.N. Stranski-Institut, Technische Hochschule, Ernst Reuter-Platz 7, D-1000, Berlin, Germany
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Abstract: | We have recomputed exact correlation diagrams for the energy of excited states; the system consists of an electron (or a different negatively charged particle) moving in the field of two fixed point chargesZ a ,Z b . The ratiosq=Z a/Zb taken into consideration here were 1, 2, and 3. In the caseq=3, three avoided crossings of energy curves belonging to states of equal symmetry type are contained in the diagram. |
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