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Dynamics of Spin Temperatures in EPR on Rapid Switching of the Frequency Detuning of a Saturating Field
Authors:V.?G.?Dubovets,I.?I.?Ugolev  author-information"  >  author-information__contact u-icon-before"  >  mailto:ugolev@ifoch.bas-net.by"   title="  ugolev@ifoch.bas-net.by"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author
Affiliation:(1) Institute of Physical and Organic Chemistry, National Academy of Sciences of Belarus, 13 Surganov Str., Minsk, 220072, Belarus
Abstract:In the framework of the spin temperature in EPR in the absence of interaction with the lattice, the time-dependent change in the spin temperatures of the Zeeman subsystem and dipole-dipole reservoir has been investigated theoretically in the high-temperature approximation. It is shown that amplification in the system can be obtained by switching the detuning of the saturating field frequency. The approach to the solution of the problem is based on the fact that during the process of switching and establishment of both temperatures the total energy of the Zeeman subsystem and of the dipole-dipole reservoir is preserved. It has been established that the values of absorption or amplification in the system depend on the frequency detunings of the saturating field. In the presence of a probe field, the possibility of determining the value of the local magnetic field related to the time of transverse relaxation of the system is demonstrated.__________Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 2, pp. 171–175, March–April, 2005.
Keywords:electronic paramagnetic resonance  spin temperature  Zeeman subsystem  dipole-dipole reservoir  magnetic susceptibility  time of transverse relaxation
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