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Synthesis and Some Chemical Conversions of 2-([2,2]-5-Paracyclophanyl)pyrrole
Authors:A V Varlamov  T N Borisova  Boniface Nsabimana  A I Chernyshev  G G Aleksandrov  L G Voskressensky
Institution:(1) Russian People's Friendship University, Moscow, 117198
Abstract:2-(2,2]-5-Paracyclophanyl)pyrrole has been synthesized and nitration and formylation of it have been effected. The 1-beta-cyanoethyl derivative and 2-formyl-5-paracyclophanyl-3H-pyrrolizine have been obtained from 5-formyl-2-(2,2]-5-paracyclophanyl)pyrrole by the action of acrylonitrile and acrolein respectively under Michael reaction conditions.
Keywords:paracyclophane  pyrrole  heterocyclization  addition  Trofimov reaction
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