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Lewis acid-mediated mono- and bis-addition of C-nucleophiles to 1,3-dioxolan-4-ones |
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| Authors: | Vitaly A. Shcherbinin Valery V. Konshin |
| Affiliation: | Department of Chemistry and High Technology, Kuban State University, Stavropolskaya st. 149, Krasnodar 350040, Russian Federation |
| Abstract: | The reactions of 1,3-dioxolan-4-ones, readily available from α-hydroxy acids and aldehydes, with C-nucleophiles are described. Two possible reaction pathways resulting in O-substituted acids and tri-(hetero)arylmethanes are shown. |
| Keywords: | 1,3-Dioxolan-4-one Oxocarbenium cation C-nucleophile 1-Alkyne Si-containing nucleophile |
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