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| 旋光性聚酰胺的合成,表征及其手性识别能力 | |
| 引用本文： | 虞斌 丁孟贤. 旋光性聚酰胺的合成,表征及其手性识别能力[J]. 功能高分子学报, 1993, 6(3): 193-198 |
| 作者姓名： | 虞斌 丁孟贤 |
| 作者单位： | 中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所 长春 130022，长春 130022，长春 130022，长春 130022，长春 130022 |
| 摘 要： | 用天然酒石酸与不同芳香二胺成盐后,经高温缩聚反应,合成了五种新的旋光性聚酰胺,讨论了聚合条件对聚合物的[α]_D~(20)值的影响以及聚合物的旋光稳定性、热稳定性。~1H-NMR及园二色(CD)谱显示聚合物的分子链存在某种有序构象。手性拆分实验初步显示所合成的聚酰胺对苯丙氨酸有手性识别能力。 |
| 关 键 词： | 旋光性聚酰胺 缩聚反应 有序构象 |
Synthesis, Characterization and Chiral Recognition Ability of Optically Active Polyamides Obtained form L-Tartaric Acid and Various Diamines |
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| Yu Bin,Ding Mengxian,Zhou Zinan,Wu Shenrong,Wang Fosong. Synthesis, Characterization and Chiral Recognition Ability of Optically Active Polyamides Obtained form L-Tartaric Acid and Various Diamines[J]. Journal of Functional Polymers, 1993, 6(3): 193-198 | |
| Authors: | Yu Bin Ding Mengxian Zhou Zinan Wu Shenrong Wang Fosong |
| Abstract: | Five new optically active polyamidcs were synthesized at high temperatures by the condensation of the salts from L-tartaric acid with diamincs. The influence of polymerization condition on the specific rotation was discussed. Based on the specific rotation,'H-NMR, CD, IR, these polyamides were found to exist in ordered conformation other than one-handed helix. Moreover, the ordered conformation was quite stable according to the plot of specific rotation versus tempertature. The primary investigation showed polyamides could discriminate the racemates of phenylalanine. |
| Keywords: | optically active polyamides high temperature polycondensation ordered conformation chiral recognition ability. |
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