Heteroligand Lanthanide Dialkyldithiocarbamate Complexes with 1,10-Phenanthroline: A New Approach to Synthesis and Application for the Preparation of Sulfides |
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| Authors: | Ivanov R A Korsakov I E Formanovskii A A Paramonov S E Kuz'mina N P Kaul' A R |
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| Institution: | (1) Moscow State University, Vorob'evy gory, Moscow, 119899, Russia;(2) Russian Academy of Sciences, Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry, ul. Miklukho-Maklaya 16/10, Moscow, 117871, Russia |
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| Abstract: | A new simple method of synthesis of heteroligand complexes Ln(Dalkdtc)3Phen] (Ln = Eu or Er; Dalkdtc is the dialkyldithiocarbamate ion, Phen is o-phenanthroline) in an aqueous solution is described; the possibility of using the complexes as initial reagents for the synthesis of rare-earth sulfides is shown. |
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