Influence of molecular organization of an azido alcohol solution on the urethane formation kinetics |
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| Authors: | S. V. Karpov V. P. Lodygina G. V. Malkov E. R. Badamshina |
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| Affiliation: | 1.Institute of Problems of Chemical Physics,Russian Academy of Sciences,Chernogolovka, Moscow Region,Russian Federation |
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| Abstract: | ![]()
The quantitative data on the influence of molecular organization of CH2Cl2 solutions of diazidopropanol and its non-azide analog (isopropanol) and the concentrations of the alcohols and catalyst (dibutyltin dilaurinate) on the kinetics of urethane formation via the reaction with 1,6-hexamethylene diisocyanate were obtained. The series of reactivity were composed for various associates of hydroxyl groups of these alcohols in solutions in the catalytic and non-catalytic reactions. |
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