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Self-assembly of nanoparticles on the surface of ionic crystals: Structural properties
Authors:K Nikolic  M Murugesan  D Cunningham  BD Moore
Institution:a Institute of Biomedical Engineering, Imperial College London, London SW7 2AZ, UK
b Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK
c Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral St, Glasgow G1 1XL, UK
Abstract:With a suitable combination of ligand-stabilised nanoparticle suspension and ionic salt solutions, it is possible to produce microcrystals that are coated with nanoparticles. The self-assembly process of coating microcrystals by gold nanoparticles (NP) is mediated by the crystal lattice. This is the so-called CLAMS process - a generic process for self-organisation of nanoparticles on the surface of crystals M. Murugeshan, D. Cunningham, J.-L. Martnez-Albertos, R. Vrcelj, B.D. Moore, Chem. Commun. (2005) 2677]. We are exploring here the structural properties of these self-assembled structures by using different imaging techniques.
Keywords:Nanoparticles  Self-assembly  Crystallization  TEM
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