Thermal decomposition of transition metal carboxylates |
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| Authors: | A S Rozenberg N Y Chukanov |
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| Institution: | (1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Chernogolovka, 142432 Moscow Region, Russian Federation |
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| Abstract: | Dynamics of changes in microstresses during thermal decomposition of Cu(HCOO)2 crystals and their effect on the thermal decomposition kinetics were studied by IR spectroscopy at 105 to 120 °C. The formation of solid intermediate HCOOCu was observed, and the dynamics of its accumulation was followed. Kinetic regularities of transformation of HCOO groups were compared with those for gas evolution.For Communication 1, see Ref. 1.Translated from Izvestiya va Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 350–354, February, 1996. |
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| Keywords: | copper(II) formate thermal decomposition IR spectroscopy microstresses |
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