Synthesis and Characterization of 5‐(1,2,4‐Triazol‐3‐yl)tetrazoles with Various Energetic Functionalities |
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Authors: | Alexander A Dippold Prof Dr Thomas M Klapötke |
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Institution: | Department of Chemistry, Ludwig‐Maximilian University of Munich, Butenandstr. 5–13 (D), 81377 Munich (Germany), Fax: (+49)?89‐2180‐77492 |
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Abstract: | In this contribution the synthesis and full structural as well as spectroscopic characterization of three 5‐(1,2,4‐triazol‐3‐yl)tetrazoles along with selected energetic moieties like nitro, nitrimino, and azido groups are presented. The main goal is a comparative study on the influence of those variable energetic moieties on structural and energetic properties. A complete characterization including IR and Raman as well as multinuclear NMR spectroscopy of all compounds is presented. Additionally, X‐ray crystallographic measurements were performed and reveal insights into structural characteristics as well as inter‐ and intramolecular interactions. The standard enthalpies of formation were calculated for all compounds at the CBS‐4M level of theory and reveal high positive heats of formation for all compounds. The calculated detonation parameters (using the EXPLO5.05 program) are in the range of 8000 m s?1 (8097 m s?1 ( 5 ), 8020 m s?1 ( 6 ), 7874 m s?1 ( 7 )). As expected, the measured impact and friction sensitivities as well as decomposition temperatures strongly depend on the energetic moiety at the triazole ring. The C? C connection of a triazole ring with its opportunity to introduce a large variety of energetic moieties and a tetrazole ring, implying a large energy content, leads to the selective synthesis of primary and secondary explosives. |
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Keywords: | energetic materials nitrogen heterocycles NMR spectroscopy X‐ray diffraction |
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