Solution stability constants of complexes of benzohydroxamic acid with some divalent metal ions |
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Affiliation: | 1. Department of Chemistry, University of Florida, Gainesville, FL, USA;2. Department of Chemistry and Physics, Augusta University, Augusta, GA, USA;1. Key Laboratory of Combinatorial Biosynthesis and Drug Discovery, Ministry of Education, Hubei Province Engineering and Technology Research Center for Fluorinated Pharmaceuticals, and Wuhan University School of Pharmaceutical Sciences, Wuhan, 430071, China;2. State Key Laboratory of Transducer Technology, Chinese Academy of Sciences, Beijing 100080, China |
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Abstract: | The thermodynamic metal-ligand stability constants of the benzohydroxamic acid with divalent metal ions Cu2+, Zn2+, Ni2+, and Mn2+ are determined in 50 volume per cent aqueous dioxane media at 35°C following the Bjerrum-Calvin titration technique as applied by Van Uitert et al. to mixed aqueous solvents. Calculations have been made by solving simultaneous equations adapting the procedure as outlined by Goldberg. |
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