Salting coefficients for gases in seawater from scaled-particle theory |
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Authors: | William L. Masterton |
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Affiliation: | (1) Department of Chemistry, University of Connecticut, 06268 Storrs, Connecticut |
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Abstract: | Experimental values of the salting coefficients for He, Ne, Ar, O2, and N2 in seawater are compared with values calculated from scaled-particle theory. The agreement is reasonably good; the average difference between calculated and observed values at 25°C is 0.007. Scaled-particle theory predicts correctly thatks should decrease as the temperature increases and that this effect should be most pronounced at low temperatures. However, the predicted magnitude ofdKs/dt is only about half of that observed. |
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Keywords: | Salting coefficient scaled-particle theory gas solubilities seawater helium neon argon oxygen nitrogen |
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