Survey of ligand field parameters of strong field d complexes obtained from the g matrix |
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| Authors: | Bruce R. McGarvey |
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| Affiliation: | Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ont., Canada N9B 3P4 |
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| Abstract: | Using a newly proposed approach involving an internally consistent set of equations, the ligand field parameters Δ/ξ, V/ξ and k are obtained from literature values of the g matrix for strong field d5 systems of various conformations in which |Δ/ξ|≤10. Qualitative analysis of the observed results is done using the Angular Overlap Model, AOM. |
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| Keywords: | Angular overlap Fe g matrix Ligand field Os Ru Strong field d5 |
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