Yttrium(III) complex with 1,10-phenanthroline: Crystal structure and spectroscopic studies |
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| Authors: | A. Moodi M. Khorasani-Motlagh M. Noroozifar B. O. Patrick |
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| Affiliation: | 1. Chemistry Department, University of Sistan & Baluchestan, Zahedan, Iran
2. Chemistry Department, University of British Columbia, Vancouver, Canada
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| Abstract: | YCl3·6H2O reacts with 1,10-phenanthroline (phen) to yield a complex of 1:2 yttrium:ligand stoichiometry. The yttrium(III) complex is characterized by the elemental analysis, UV-Vis, IR as well as the X-ray diffraction analysis. The crystal of [Y(phen)2Cl(H2O)3]Cl2·H2O obtained from a methanol solution crystallizes in the triclinic system, space group P 337-1, Z = 2, a = 10.3236(4) Å, b = 10.4566(4) Å, c = 12.5270(5) Å, α = 97.354(2)°, β = 108.740(2)°, γ = 93.458(2)°, R int = 0.046. The Y(III) ion is eight-coordinated by four nitrogen, three oxygen atoms and one chlorine atom. |
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