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Isotope shift in chromium
Institution:1. Lebedev Physical Institute, 443011, Samara, Russia;2. Samara National Research University, 443086, Samara, Russia;1. Department of Analytical Chemistry, Nutrition and Food Sciences, P.O. Box 99, 03080 Alicante, Spain;2. Den – Service d''Etudes Analytiques et de Réactivité des Surfaces (SEARS), CEA, Université Paris-Saclay, F-91191 Gif sur Yvette, France;3. Den – Département de Physico-Chimie (DPC), CEA, Université Paris-Saclay, F-91191 Gif sur Yvette, France;1. Department of Physics, Florida A&M University, 2077 E. Paul Dirac Drive, Tallahassee, FL 32310, United States;2. Alakai Defense Systems, 197 Replacement Ave, Suite 102, Fort Leonard Wood, MO 65473, United States
Abstract:Thirty-three spectral lines of chromium atom in the blue-violet region (425–465 nm) have been investigated with the method of laser-induced resonance fluorescence on an atomic beam. For all the lines, the isotope shifts for every pair of chromium isotopes have been determined. The lines can be divided into six groups, according to the configuration of the upper and lower levels. Electronic factors of the field shift and the specific mass shift (Fik and MikSMS, respectively) have been evaluated and the values for each pure configuration involved have been determined. Comparison of the values Fik and MikSMS to the ab initio calculations results has been performed. The presence of crossed second order (CSO) effects has been observed.
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