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First stereoselective total synthesis of seimatopolide A |
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| Authors: | Gowravaram Sabitha A. Yagundar ReddyJ.S. Yadav |
| Affiliation: | Natural Product Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 607, India |
| Abstract: | The first stereoselective total synthesis of seimatopolide A (1) has been achieved. The key steps are Keck allylation, Sharpless asymmetric dihydroxylation, cross-, and ring-closing metathesis reactions. |
| Keywords: | Natural product Keck allylation Cross-metathesis Sharpless dihydroxylation Ring-closing metathesis |
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