The vuv photoelectron spectra of atomic In and Tl

The photoelectron spectra of atomic indium and thallium have been obtained using a pseudo-atomic beam technique. Ionizations from the np, ns and (n ? 1)d shells (n = 5 for In and n = 6 for Tl) were observed using He(I) and HE(II) radiation. The (np)^?1 ionization results in a single ¹S₀ ionized state, whereas the (ns)^?1 and ((n ? 1)d)^?1 ionizations both result in states additional to those allowed for a one-electron ionization process. This is attributed to configuration interaction in the final ionized state.