| 一种含[Ni(CN)4]2-和[Cu(pn)]2+构筑元组成的超分子配合物的合成、单晶结构和磁学性质 |
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| 引用本文： | 苏育志,刘兆清,董文.一种含[Ni(CN)4]2-和[Cu(pn)]2+构筑元组成的超分子配合物的合成、单晶结构和磁学性质[J].无机化学学报,2007,23(4):713-716. |
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| 作者姓名： | 苏育志 刘兆清 董文 |
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| 作者单位： | 广州大学化学化工学院,化学系,广州,510006 |
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| 摘 要： | A cyano-bridged heterometallic supramolecular complex {Cu(pn)]3Ni(CN)4]3}n (1) has been synthesized and structurally characterized by single crystal X-ray diffraction. 1 displays an interesting 3D structure formed by μ4, μ3-Ni(CN)4]2- tectons bridging five-coordinated and six-coordinated Cu(II) ions. The magnetic property shows that 1 behaves as weakly ferromagnetic interactions between the adjacent Cu(II) ions through the diamagnetic spacer NC-Ni-CN. CCDC: 624387.
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| 关 键 词： | 超分子配合物 单晶结构 磁性 |
| 文章编号： | 1001-4861(2007)04-0713-04 |
| 修稿时间： | 2007-02-01 |
Synthesis, Crystal Structure and Magnetic Property of a Cyano-Bridged 3D Heterometallic Supramolecular Complex Containing [Ni(CN)4]2- and [Cu(pn)]2+ Tectons |
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| SU Yu-Zhi,LIU Zhao-Qing and DONG Wen.Synthesis, Crystal Structure and Magnetic Property of a Cyano-Bridged 3D Heterometallic Supramolecular Complex Containing [Ni(CN)4]2- and [Cu(pn)]2+ Tectons[J].Chinese Journal of Inorganic Chemistry,2007,23(4):713-716. |
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| Authors: | SU Yu-Zhi LIU Zhao-Qing and DONG Wen |
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| Institution: | Department of Chemistry, School of Chemical Engineering and Technology, Guangzhou University, Guangzhou 510006,Department of Chemistry, School of Chemical Engineering and Technology, Guangzhou University, Guangzhou 510006 and Department of Chemistry, School of Chemical Engineering and Technology, Guangzhou University, Guangzhou 510006 |
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| Abstract: | A cyano-bridged heterometallic supramolecular complex{Cu(pn)]3Ni(CN)4]3}n(1)has been synthesized and structurally characterized by single crystal X-ray diffraction.1 displays an interesting 3D structure formed by μ4,μ3-Ni(CN)4]2- tectons bridging five-coordinated and six-coordinated Cu(Ⅱ)ions.The magnetic property shows that 1 behaves as weakly ferromagnetic interactions between the adjacent Cu(Ⅱ)ions through the diamagnetic spacer NC-Ni-CN.CCDC:624387. |
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| Keywords: | supramolecular complex single crystal structure magnetic property |
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