| Structural Chemistry of Heteroselenometallic Clusters |
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| 作者姓名： | 张千峰 曹荥 等 |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structureof Matter，the Chinese Academy of Sciences，Fuzhou，Fujian，350002，China |
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| 摘 要： | 1INTRoDUCTIoNThechemistryofMS'j'-(M=Mo,W)anionsandtheirrelatedcompoundshavebeenextensivelyinvestigatedfortheirrelevancetobiologicalsystem,richstruc-turalchemistryandspecialreactivepropertiesaswellaspotentialapplicationinnon-linearopticalmaterials,t1~5iwhereasthatofMSe'j'-(M=Mo,W)anionsandtheirrelatedcompoundshavereceivedattentiononlyinrecentyears.t6~7)Inl989lMhllerisolatedtwoclustercompounds,namely,cubane-likeOMoSe3Cl-(CuPPh,),j(siandlinearWSe'(AgPPh,),).t9iAfterthat,lbersstud…
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| 关 键 词： | 结构化学 硒钨酸 原子族合物 硒钼酸 |
Structural Chemistry of Heteroselenometallic Clusters |
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| ZHANG Qian-Feng, CAO Rong HONG, Mao-Chun, LIU Han-Qin,LU Jia-Xi.Structural Chemistry of Heteroselenometallic Clusters[J].Chinese Journal of Structural Chemistry,1998,17(2):112-118. |
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| Authors: | ZHANG Qian-Feng CAO Rong HONG Mao-Chun LIU Han-Qin LU Jia-Xi |
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| Institution: | [1]StatekeyLaboratoryofStructuralChemistry,FujianInst [2]StatekeyLaboratoryofStructura,FujianInst |
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| Abstract: | About forty heterobimetallic clusters with selenotungstate or se-lenomolybdate showing ten structural types of linear, butterfly, cubane-like, defective-cubane, planar and cage etc. are systematically classified and summarized, and severalsuggestions were proposed, which might be useful for further research on structuralchemistry of heteroselenometallic clusters. |
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| Keywords: | structural chemistry heteroselenometallic cluster selenotungstate selenomolybdate |
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