| Synthesis and Crystal Structure of a Copper(Ⅱ) Compound with 4-Hydroxybenzoic Acid and Isonicotinamide:[Cu(4-hba)_2(inta)(H_2O)]·H_2O |
| |
| 作者姓名： | HONG Li LI Xiu-Mei WANG Qing-Wei XU Zhan-Lin LIU Bo |
| |
| 作者单位： | HONG Li,XU Zhan-Lin,LIU Bo(College of Chemistry,Jilin Normal University,Siping 136000,China);LI Xiu-Mei(College of Chemistry,Jilin Normal University,Siping 136000,China; Department of Chemistry,Tonghua Teachers College,Tonghua 134002,China);WANG Qing-Wei(Department of Chemistry,Tonghua Teachers College,Tonghua 134002,China) |
| |
| 基金项目： | The project was supported by the Education Office of Jilin Province （No. 0047） |
| |
| 摘 要： | A new copper(Ⅱ) compound has been prepared and fully characterized by elemen-tal analysis,IR,TG and single-crystal X-ray diffraction.The compound Cu(4-hba)2(inta)(H2O)]·H2O (4-hba=4-hydroxybenzoic acid,inta=isonicotinamide) 1 crystallizes in the monoclinic system,space group P21/c with a=7.590(5),b=11.027(5),c=23.761(5),β=102.5740(10)o,V=1974.1(16) 3,Mr=991.84,Z=2,Dc=1.669 g/cm3,F(000)=1020,μ=1.166 mm-1,R=0.0353 and wR=0.0604 for 3166 observed reflections (I 2σ(I)).In compound 1,the copper cation is penta-coordinated with two carboxylate oxygen atoms from two different 4-hba ligands,two oxygen atoms from two coordinated water molecules and one nitrogen atom from inta ligand,showing a slightly distorted square-pyramidal geometry.
|
| 关 键 词： | 铜（Ⅱ） HBA 水分子 羟基酸 H2O 复合结构 晶体 配位化合物 |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
