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Oxidative addition of dialkylphosphine oxides and of alkyl alkylphosphonites to iridium(I)
Authors:T.R.B. Mitchell
Affiliation:Department of Chemistry, Queen''s University, Belfast BT9 SAG N. Ireland
Abstract:Dimethyl- and diethyl-phosphine oxide, methyl methylphosphonite and ethyl methylphosphonite all oxidatively add to (Me2PhP)3IrCl, generated in situ, to give hydrido(dialkylphosphinito)- or alkyl (alkylphosphonito)-iridium(III) complexes.
Keywords:
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