The electrochemical reduction of an unsaturated mixed-metal cluster anion: Synthesis and x-ray crystal structure of [(Ph3P)2N][{Os3H(CO)10}2Ag] |
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| Authors: | Mariano Fajardo M Pilar Gómez-Sal HDiane Holden Brian FG Johnson Jack Lewis Roderick CS McQueen Paul R Raithby |
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| Institution: | University Chemical Laboratory, Lensfield Road, Cambridge, CB2 1EW Great Britain |
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| Abstract: | The unsaturated mixed-metal cluster anion {Os3H(CO)10}2Ag]? has been prepared by the reaction of (Ph3P)2N]Os3H(CO)11] with AgPF6], and the anion has been shown by an X-ray analysis to consist of an AgI atom linking together two “Os3H(CO)10” fragments. The electrochemistry of this complex has been investigated and it has been shown to undergo two one-electron reductions. |
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