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| 铬系乙烯齐聚和聚合催化剂 | |
| 引用本文： | 刘元霞,方义群,宋炬伟,李伟,胡友良. 铬系乙烯齐聚和聚合催化剂[J]. 高分子通报, 2002, 0(2): 29-37 |
| 作者姓名： | 刘元霞 方义群 宋炬伟 李伟 胡友良 |
| 作者单位： | 1. 中国科学院化学研究所,分子科学研究中心,工程塑料国家重点实验室,北京,100080 2. 辽宁省营口市向阳化工总厂,营口,115005 |
| 基金项目： | 国家自然科学基金 (NO .2 9734 1 4 1 )，SINOPEC联合资助 |
| 摘 要： | 综述了近年来国内外铬系催化剂的最新研究进展。介绍了该类催化剂齐聚和合的性能研究和应用，讨论了该催化剂长期引起争议的活性中心，活性价态，以及反应机理，并同时预测了铬系催化剂在工业和纳米技术方面的发展趋势。 |
| 关 键 词： | 铬系催化剂 乙烯 齐聚 聚合 聚乙烯 催化活性 |
Chromium-based catalyst for Ethylene Oligomerization and Polymerization |
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| LIU Yuan|xia+,FANG Yi|qun+,SONG Ju|wei+,LI Wei+,HU You|liang+. Chromium-based catalyst for Ethylene Oligomerization and Polymerization[J]. Polymer Bulletin, 2002, 0(2): 29-37 | |
| Authors: | LIU Yuan|xia+ FANG Yi|qun+ SONG Ju|wei+ LI Wei+ HU You|liang+ |
| Affiliation: | LIU Yuan|xia+1,FANG Yi|qun+1,SONG Ju|wei+2,LI Wei+2,HU You|liang+1 |
| Abstract: | In this Paper,recent advances of the chromium|based catalysts developed,at home and abroad,were reviewed.From the incisive analysis based on the documents collected,and a longstanding debate over questions about chemical nature of the active site(s),the oxidation state of active chromium,and the mechanism of initiation has been resoluted,it was concluded that chromium|based catalysts would continue to play an important role in ethylene industry and take up some fields in nanocomposite materials in coming years. |
| Keywords: | Chromium based catalyst Ethylene Oligomerization Polymerization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |