Crystal structure of a barium-zinc decametaphosphate Ba2Zn3P10O30 |
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Authors: | M Bagieu-Beucher A Durif JC Guitel |
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Institution: | Laboratoire de Cristallographie, Centre National de la Recherche Scientifique, Laboratoire associé à l''USMG, 166X, 38042 Grenoble Cédex, France |
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Abstract: | Barium-zinc decametaphosphate, Ba2Zn3P10O30, is monoclinic, , with the unit cell parameters a = 21.738(15), b = 5.356(5), c = 10.748(8) Å, β = 99.65(3)° and Z = 2. The crystal structure was solved with a final R value of 0.041. This salt provides the first structural evidence for the existence of a 10-phosphorus ring anion. |
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