|
|||||
|
|
| (CH3)2N(C6H4)nCN系列分子二阶非线性光学系数的理论研究 | |
| 引用本文： | 于宏石,封继康,李君,李志儒.(CH3)2N(C6H4)nCN系列分子二阶非线性光学系数的理论研究[J].化学学报,1993,51(4):334-340. |
| 作者姓名： | 于宏石 封继康 李君 李志儒 |
| 作者单位： | 吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系 长春 130023，长春 130023，长春 130023，长春 130023 |
| 摘 要： | 在AM1和INDO/CI方法的基础上, 用自编程序计算了(CH3)2N(C6H4)nCN(n=1→6)系列分子的二阶非线性光学系数β~i~j~k和β~μ并系统地研究了共轭链长对分子二阶非线性光学系统的影响及β~μ对激光场频率的依赖关系(色散效应) |
| 关 键 词： | 计算机应用 联苯胺 P 非线性光学 苯甲腈 P 色散 微分重叠间忽略近似 仲胺 P |
A theoretical study of the nonlinear optical second-order susceptibilities of (CH3)2N(C6H4)nCN series molecules |
|
| Abstract: | Based on AM1 and INDO/CI methods, using the program for calcns. of the nonlinear optical second-order susceptibilities (bijk), (bijk) and (bm) were calculated for (CH3)2N(C6H4)nCN series mols., n = 1 ?6. A systematic study is reported of the effect of conjugation length on the mol. nonlinear optical second-order susceptibilities and investigated the laser frequency dependences (dispersions) of (bm) are discussed. |
| Keywords: | COMPUTER APPLICATIONS BENZIDINE P NON LINEAR OPTICS BENZONITRILE P DISPERSION INTERMEDIATE NEGLECT OF DIFFERENTIAL OVERLAP APPROXIMATION (IND SECONDARY AMINE P |
| 本文献已被 CNKI 维普 等数据库收录！ | |
| 点击此处可从《化学学报》浏览原始摘要信息 | |
| 点击此处可从《化学学报》下载免费的PDF全文 | |