| Synthesis, Crystal Structure and Fluorescent Property of One New Complex [Na2（2-benzoylbenzoato）4（Phen）2（H2O）2]·H2O |
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| 作者姓名： | 杨颖群 张少华 唐斯萍 付立夏 |
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| 作者单位： | Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang;Hengyang Xicheng Organic Chemical Plant, Hengyang |
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| 基金项目： | Supported by the Fund of Science and Technology Committee of Hunan Province(No.2012GK3030);the Scientific Research Fund of Hunan Provincial Education Department(No.B21018);the Hengyang Bureau of Science & Technology(No.2011kG28);the Science Technology Foundation of Hunan Province(No.2012FJ3020);the Natural Science Foundation of Hunan Province(No.12JJ6013) |
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| 摘 要： | One binuclear sodium(Ⅰ) complex [Na2(2-benzoylbenzoato)4(Phen)2(H2O)2]·H2O has been synthesized with 2-benzoylbenzoic acid and 1,10-henanthroline as ligands. The crystal structure was determined by X-ray diffraction. The crystal belongs to the triclinic system with space group P , a = 1.08096(8), b = 1.09619(8), c = 1.09740(8) nm, α = 79.0600(1), β = 71.0450(1), γ = 62.0540(1)o, V = 1.08533(1) nm3, Dc = 1.421 g/cm3, Z = 2, F(000) = 484, GOOF = 1.036, the final R = 0.0363 and wR = 0.0961. The crystal structure shows that two neighboring sodium(Ⅰ) ions are linked together by two bridging water molecules, and each end position is coordinated with one 1,10-phenanthroline molecule and one 2-benzoylbenzoato to form a binuclear structure. Each sodium(Ⅰ) ion in the molecule is coordinated with five atoms to give a distorted trigonal bipyramid. The fluorescence property of the title complex is also discussed.
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| 关 键 词： | sodium(Ⅰ) complex 2-benzoylbenzoic acid crystal structure fluorescence property |
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