Pulse photolysis rate constants of the decay of ester peroxide radicals |
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| Authors: | A I Nikolaev V S Martemianov R L Safiullin and L G Ibragimova |
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| Institution: | (1) Institute of Chemistry, Ufa, USSR |
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| Abstract: | Pulse photolysis measurements of rate constants of the decay of peroxide radicals for seven saturated acetates have revealed their increase with shortening alkyl chain. It is attributed to the high rate constants of the interaction of  -acyloxyperoxide radicals ((3±1)×108l/mol s) compared to those for remote peroxide ones.
                           .   ,  - (3±1)×108 /. )     .
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