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Reaction of α-haloester having internal double bond with the low-valent metal complex
Authors:Miwako Mori  Yukiko Kubo  Yoshio Ban
Institution:Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060 Japan
Abstract:The α-haloester having an internal double bond was allowed to react with a catalytic amount of Pd(PPh3)4 to afford a cyclized product in a fairly good yield and the same product was obtained by treatment with Pd(OAc)2 to ketene silyl acetal.
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