Palladium-catalyzed carbonylation of enol triflates. A novel method for one-carbon homologation of ketones to α,β-unsaturated carboxylic acid derivatives |
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| Authors: | Sandro Cacchi Enrico Morera Giorgio Ortar |
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| Affiliation: | 1. Istituto di Chimica Organica dell'' Universitá, via del Castro Laurenziano 9, 00161 Roma, Italy.;2. Centro di Studio per la Chimica del Farmaco del C.N.R., Istituto di Chimica Farmaceutica dell'' Universitá, 00185 Roma, Italy |
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| Abstract: | ![]()
Ketones can be homologated to α,gb-unsaturated esters or amides via their enol triflates by a palladium-catalyzed reaction with carbon monoxide and alcohols or amines. |
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