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Synthesis of new norbornenones with the aminoester group methyl bicyclo [2-2-1] hept 5-ene 7-one 1-amino 2-carboxylates
Authors:Mireille Bourhis  René Golse  Michel Goursolle  Philippe Picard
Affiliation:(UA 605) Laboratoire de Chimie Générale, Université de Bordeaux II, 33076 Cedex, France;Laboratoire de Cristallographie UA 144, Université de Bordeaux I, 33405 Cedex, France
Abstract:
Amino norbornenonecarboxylates were synthesized from methyl acrylate and amino butadienecarboxylates. This result is equivalent of amino cyclopentadienones Diels-Alder reaction. Amino butadienecarboxylates were prepared by prototropic transposition of the β-allenic aminoesters.
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